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Phenol

CAS

Purity

Category

Nickname

: 108-95-2

: 99.50%

: Phenolic Ketone 

:PHENOL; PHENOL,INDUSTRIAL; Fenol; ACSPHENOLCRYSTALS; PHENOL CRYSTALS ANALAR; Phenole; PHENOL SOLID; Phenol water saturated sol.,DNAse,RNAse; Paoscle; PHENOL FOR SYNTHESIS; PHENOL - WHOLE VOLUME, CRM STANDARD; Phenol; CARBOLIC ACID; PHENOL, MOLTEN; LIQUEFIED PHENOL; Hydroxybenzene; PhOH; Fenolo; NA 2821; PHENOL BP (DETACHED CRYSTALS); Izal; BENZENOL;
:PHENOL; PHENOL,INDUSTRIAL; Fenol; ACSPHENOLCRYSTALS; PHENOL CRYSTALS ANALAR; Phenole; PHENOL SOLID; Phenol water saturated sol.,DNAse,RNAse; Paoscle; PHENOL FOR SYNTHESIS; PHENOL - WHOLE VOLUME, CRM STANDARD; Phenol; CARBOLIC ACID; PHENOL, MOLTEN; LIQUEFIED PHENOL; Hydroxybenzene; PhOH; Fenolo; NA 2821; PHENOL BP (DETACHED CRYSTALS); Izal; BENZENOL;
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$1050

size/weight : Bulk drum IOS Tank

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CHARACTER

phenol, chemical formula C6H6O, is a colorless crystal with a special smell, melting point 40.5 ℃, boiling point 181.7 ℃, molecular weight 94.11. It is an important organic chemical raw materials and intermediates, widely used in synthetic fibers, plastics, pesticides, pharmaceuticals, dyes and spices and other industries. Phenol can react with a variety of compounds to produce a variety of derivatives, which are of great value in chemical production. In the synthetic fiber industry, phenol is used to produce caprolactam and nylon 66; in the plastics industry, it is the raw material for the manufacture of phenolic resins and epoxy resins; in the pesticide industry, phenol is used to synthesize a variety of herbicides and pesticides; In addition, phenol is also used to produce pharmaceutical intermediates, dyes and spices. As a multifunctional chemical raw material, phenol is widely used in industrial production.

APPLICATIONS

phenol is an important organic chemical raw material, which can be used to produce phenolic resin, caprolactam, bisphenol A salicylic acid, picric acid, pentachlorophenol, 2,4-D adipic acid, phenolphthalein n- acetoethoxyaniline and other chemical products and intermediates have important uses in chemical raw materials, alkyl phenols, synthetic fibers, plastics, synthetic rubber, pharmaceuticals, pesticides, spices, dyes, coatings and oil refining industries. In addition, phenol can also be used as a solvent, experimental reagents and disinfectants, and the aqueous solution of phenol can make proteins on chromosomes in plant cells and DNA separation, easy DNA staining was performed.

ABILITIES

1. Packing: barreled, scattered water

2. Logistics: car transportation, shipping

3. Payment request: EXW/FOB/FCA/CFR only accepted

HONORARY

Chinese name Phenol
English Name Phenol
Alias Phenol
Carbolic
Carbonic
Hydroxybenzene
Industrial Phenol
Solid Phenol

of Phenol Crystals Coking Phenol

Phenol, Carbonic Phenol PHENOL
English alias Phenol
OXYBENZENE
PHENOL USP
PHENIC ACID
phenol, pure
Coking phenol
hydroxybenzol
DetailsPhenol
PHENOL REAGENT
Hydroxybenzene
PHENOL LIQUIFIED
PHENOL, LIQUEFIED
Poly(4-hydroxy)styrene
PHENOL SATURATED, PH 4.5
Phenol detached crystals
Phenol, MB Grade (1.07632)
PHENOL,FUSEDCRYSTAL,TECHNICAL
LIQUEFIEDPHENOL,LIQUEFIED,USP
CAS 108-95-2
EINECS 203-632-7
Chemical formula C6H6O
molecular weight 94.11
InChI InChI=1/C6H6O/c7-6-4-2-1-3-5-6/h1-5,7H
InChIKey ISWSIDIOOBJBQZ-UHFFFAOYSA-N
Density 1.071g/mLat 25°C(lit.)
melting point 40-42°C(lit.)
boiling point 182°C(lit.)
Flash Point 175°F
water solubility 8 g/100 mL
Vapor pressure 0.09 psi ( 55 °C)
steam density 3.24 (vs air)
JECFA Number 690
solubility H2O: 50 mg/mL at 20°C, clear, colorless
refractive index n20/D 1.53
acidity coefficient 9.89(at 20℃)
PH value 6.47(1 mM solution);5.99(10 mM solution);5.49(100 mM solution);
Storage conditions 2-8°C
Sensitivity Air & Light Sensitive
Appearance Solid
Specific Gravity 1.071
Color faintly yellow
Smell Sweet, medicinal odor detectable at 0.06 ppm
Merck 14,7241
BRN 969616
explosion limit value 1.3-9.5%(V)
Exposure Limits TLV-TWA skin 5 ppm (~19 mg/m3 )(ACGIH, MSHA, and OSHA); 10-hour TWA 5.2 ppm (~20 mg/m3 ) (NIOSH); ceiling60 mg (15 minutes) (NIOSH); IDLH 250ppm (NIOSH).
physicochemical properties colorless needle crystal or white crystal frit. There is a special odor and burning smell, very dilute solution has a sweet taste. Soluble in ethanol, ether, chloroform, glycerin, carbon disulfide, petroleum jelly, volatile oil, fixed oil, strong alkali aqueous solution. Almost insoluble in petroleum ether.
Dangerous Goods Signs T-Toxic
Materials C- Corrosive Materials
F-Flammable Materials
Xn-Hazardous Materials
Risk Terms R23/24/25-Toxic by inhalation, skin contact and swallowing.
, R34-causes burns.

R48/20/21/22 -R68-May risk of irreversible consequences.
-R40-Few reported carcinogenic consequences.

R39/23/24/25 -R11-Highly flammable.
, R36-Irritating to eyes. R20/21/22-
Harmful by inhalation, skin contact and swallowing.
R24/25 -
Safety terminology S26-After eye contact, rinse immediately with plenty of water and seek medical advice.
-S36/37/39-Wear appropriate protective clothing, gloves and goggles or masks.
-S45-In case of accident or feeling unwell, seek medical attention (if possible, show their label).
, S36/37-Wear appropriate protective clothing and gloves.

S28A -S28-After contact with skin, immediately rinse with plenty of soapy water.
, S24/25-Avoid skin and eye contact. S1/2-Lock the
and keep it out of the reach of children.

, S36-Wear suitable protective clothing.
, S16-Keep away from ignition sources.
-S7-Keep container sealed.
Dangerous Goods Transport Number UN 2821 6.1/PG 2
WGK Germany 2
RTECS SJ3325000
FLUKA BRAND F CODES 8-23
TSCA Yes
Customs number 29071100
Hazard Class 6.1
Packing Group II
Upstream raw materials Benzene Cresol Sulfate Sodium Hydroxide Cumene
Downstream Products Sodium sulfite diphenyl ether D-p-hydroxyphenylglycine 2,4, 6-trichlorophenol

Phenol-Properties

Colorless needle crystals or white crystals. There is a special odor, very dilute solution has a sweet taste. The impure product becomes light red or red under the action of light and air, and changes color faster in case of alkali. Rate 11 54178. Flash point 79. 44 ℃ (closed cup).85 ℃ (open cup), spontaneous ignition point 715 ℃, combustion limit of vapor and air mixture 1_ 7~8.6%. Flammable, strong corrosion. Toxic. 1g phenol is dissolved in about 15mL water (0.67%, can be dissolved in any proportion after heating at 25 ℃), 12mL benzene. Soluble in ethanol, ether, chloroform, glycerin, carbon disulfide, petroleum jelly, volatile oil, fixed oil, strong alkali aqueous solution. Almost insoluble in petroleum ether. The pH of the aqueous solution was about 6.0.

phenol-preparation method

There are mainly sulfonation method and cumene method. Sulfonation method is based on benzene as raw material, with sulfuric acid for sulfonation to produce benzene sulfonic acid, with sulfurous acid neutralization, and then caustic soda alkali fusion, through the steps of sulfonation and vacuum distillation. Cumene method is propylene and benzene under the action of aluminum trichloride catalyst to produce cumene, cumene is oxidized to produce cumene hydroperoxide, and then decomposed with sulfuric acid to obtain phenol and acetone.

Phenol-Standard

This product contains not less than 99.0% C6H6O.

phenol-character

  • This product is colorless to reddish acicular crystals or crystalline blocks; smelly; hygroscopic; aqueous solution shows weak acid reaction; in case of light or in the air color gradient deep.
  • This product is soluble in ethanol, chloroform, ether, glycerin, fatty oil or volatile oil, soluble in water, slightly soluble in liquid paraffin.

condensation point

The freezing point of this product (general 0613) is not less than 40°C.

Phenol-Uses

It is used in oil field industry and is also an important organic chemical raw material. It can be used to prepare phenolic resin, caprolactam, bisphenol A, salicylic acid, picric acid, pentachlorophenol, phenolphthalein, N-acetoxyaniline and other chemical products and intermediates. It is widely used in chemical raw materials, alkyl phenols, synthetic fibers, plastics, synthetic rubber, medicine, pesticides, spices, dyes, coatings and oil refining industries.

Phenol-Identification

Take 0.1g of this product, add 10ml of water to dissolve it, and test it according to the following method.

  1. Take 5ml of solution and add 1 drop of ferric chloride test solution to show blue-purple color.
  2. Take 5ml of solution and add bromine test solution to generate instant dissolved white precipitate, but when bromine test solution is excessive, permanent precipitate will be generated.
  3. The infrared absorption spectrum of this product should be consistent with the control spectrum (spectral set 240 diagram).

Phenol-Safety

  • Rat oral LD 50 530 mg/kg. The phenol vapor condenses into dust in the cooler air. Contact with skin can cause poisoning. When the skin comes into contact with phenol aqueous solution or pure phenol, it is quickly stimulated to produce local anesthesia, which in turn becomes an ulcer. General acute poisoning has a sense of weakness, showing vertigo, tinnitus, sweating. In the body can damage the kidney. The production site equipment shall be sealed. Operators should wear protective equipment. The maximum allowable concentration in the air of the workplace is 5 × 10-6.
  • Packed in galvanized iron drums, 200kg per barrel, stored in a dry and ventilated warehouse below 35 ℃. Sun and rain are strictly prohibited. Fire and heat sources are isolated to prevent violent impact. The storage period is three months. It is forbidden to transport together with gunpowder and oxidizing substances such as peroxides.

Phenol-check

Take 5.0g of non-volatile matter, steam it in a water bath, and dry it to constant weight at 105°C. The remaining residue shall not exceed 2.5mg.

phenol-determination of content

Take about 0.15g of this product, weigh it accurately, place it in a 100ml volumetric flask, add appropriate amount of water to dissolve and dilute to scale, shake well; Accurately measure 25ml, place it in an iodine bottle, add 30ml of bromine titration solution (O.05mol/L), add 5ml of acid, plug immediately, shake for 30 minutes, stand for 15 minutes, pay attention to slightly uncorking, add 6ml of potassium iodide test solution, and plug immediately, after full shaking, add 1ml of chloroform to shake well, titrate with sodium thiosulfate titration solution (0.lmol/L, add starch indicator solution near the end point, continue titration until blue disappears, and correct the titration result with blank test. Each 1 ml of bromine titrate (0.05mol/L) corresponds to 1.569mg of C6H6O.

Phenol-Category

Disinfection antiseptic.

Phenol-Storage

Shading, sealed preservation.

Phenol-Introduction

Phenol, also known as hydroxybenzene, is an organic compound. The following is an introduction to the properties, uses, preparation and safety information of phenol:

properties:
-appearance: colorless to white crystalline solid.
-Solubility: Soluble in water and most organic solvents.
-Odor: Has a special phenolic odor.
-Reactivity: Phenol is acid-base neutral and can react with other substances in acid-base, oxidation and substitution reactions.

use:
-chemical industry: phenol is widely used in the synthesis of phenol formaldehyde, phenol ketone and other chemicals.
-Preservative: Phenol can be used as a wood preservative, disinfectant and germicide.
-rubber industry: can be used as rubber additives, improve the viscosity of rubber.

preparation method:
-The common method for preparing phenol is through the oxidation reaction of oxygen in the air. Phenol can also be prepared by demethylation of catechol.

Safety Information:
-Phenol is toxic and irritating to the skin, eyes and respiratory tract. After contact should be washed with water immediately, and timely medical treatment.
-Exposure to high concentrations of phenol can cause symptoms of poisoning, including dizziness, nausea, and vomiting. Long-term exposure may cause damage to the liver, kidneys, and central nervous system.
-During storage and use, appropriate safety measures need to be taken, such as wearing protective gloves, glasses, etc. Operate in a well-ventilated area.

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Chemical Safety Data Sheet MSDS / SDS

Phenol

Revision Date:2024-10-26Revision Number:1
 

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: Phenol
  • CBnumber: CB4362168
  • CAS: 108-95-2
  • EINECS Number: 203-632-7
  • Synonyms: Phenol,PhOH

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company: SKYSEVEN CHEM
  • Address: 9F,Block B,WOLl Center, Lane 2157, Hu Nan RoadPudong New District, Shanghai,China
  • Telephone:  +86-21-50179788

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

  • Symbol(GHS)
  • Signal wordDanger
Precautionary statements
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P307+P311 IF exposed: call a POISON CENTER or doctor/physician.
P310 Immediately call a POISON CENTER or doctor/physician.
P311 Call a POISON CENTER or doctor/physician.
P405 Store locked up.
P501 Dispose of contents/container to..…
Hazard statements
H225 Highly Flammable liquid and vapour
H227 Combustible liquid
H301 Toxic if swalloed
H302 Harmful if swallowed
H311 Toxic in contact with skin
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H319 Causes serious eye irritation
H331 Toxic if inhaled
H332 Harmful if inhaled
H340 May cause genetic defects
H341 Suspected of causing genetic defects
H360 May damage fertility or the unborn child
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H373 May cause damage to organs through prolonged or repeated exposure
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects

SECTION 3: Composition/information on ingredients

Substance

  • Product name: Phenol
  • Synonyms: Phenol,PhOH
  • CAS: 108-95-2
  • EC number: 203-632-7
  • MF: C6H6O
  • MW: 94.11

SECTION 4: First aid measures

Description of first aid measures

General advice
First aider needs to protect himself. Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.
In case of skin contact
After contact with skin: rinse out with polyethylene glycol 400 or a mixture of polyethylene glycol 300/ethanol 2:1 and wash with plenty of water. If neither is available wash with plenty of water. Immediately take off contaminated clothing. Call a physician immediately.
In case of eye contact
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.
If swallowed
If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. Do not attempt to neutralise.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.For this substance/mixture no limitations of extinguishing agents are given.

Special hazards arising from the substance or mixture

Carbon oxides Combustible.

Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating.

Development of hazardous combustion gases or vapours possible in the event of fire.

Advice for firefighters

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Further information

Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system.

 


SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Avoid generation and inhalation of dusts in all circumstances. Avoid substance contact. Ensure adequate ventilation. Keep away from

heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

For personal protection see section 8.

Environmental precautions

Do not let product enter drains.

Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully. Dispose of properly. Clean up affected area. Avoid generation of dusts.

Reference to other sections

For disposal see section 13.


SECTION 7: Handling and storage

Precautions for safe handling

Work under hood. Do not inhale substance/mixture.

Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.

For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.

Handle and store under inert gas. Light sensitive.

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated


SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits
Does not contain substances with occupational exposure limits.

Exposure controls

Appropriate engineering controls

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Personal protective equipment
Eye/face protection

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Skin protection

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Full contact Material: Viton?

Minimum layer thickness: 0,7 mm Break through time: 480 min

Material tested:Vitoject? (KCL 890 / Aldrich Z677698, Size M)

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Splash contact Material: Viton?

Minimum layer thickness: 0,7 mm Break through time: 480 min

Material tested:Vitoject? (KCL 890 / Aldrich Z677698, Size M)

Body Protection

Flame retardant antistatic protective clothing.

Respiratory protection

required when dusts/vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Control of environmental exposure

Do not let product enter drains.

Exposure limits
TLV-TWA skin 5 ppm (~19 mg/m3 ) (ACGIH, MSHA, and OSHA); 10-hour TWA 5.2 ppm (~20 mg/m3 ) (NIOSH); ceiling 60 mg (15 minutes) (NIOSH); IDLH 250 ppm (NIOSH).

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

  • Appearance solid
  • Odourstinging
  • Odour Threshold0,005 ppm
  • pHca.5 at 50 g/l at 20 °C
  • Melting point/freezing pointMelting point/range: 40 - 42 °C - lit.
  • Initial boiling point and boiling range182 °C - lit.
  • Flash point79,0 °C - closed cup
  • Evaporation rateNo data available
  • Flammability (solid, gas)No data available
  • Upper/lower flammability or explosive limits Upper explosion limit: 9,5 %(V) Lower explosion limit: 1,3 %(V)
  • Vapour pressure 0,53 hPa at 20,0 °C
  • Vapour density 3,2 at 20 °C - (Air = 1.0)
  • Relative density1,071 g/cm3 at 25 °C
  • Water solubility87 g/l at 25 °C
  • Partition coefficient: n-octanol/waterlog Pow: 1,47 at 30 °C - (ECHA), Bioaccumulation is not expected.
  • Autoignition temperature715 °C at 1.013 hPa
  • Decomposition temperatureNo data available
  • ViscosityNo data available
  • Explosive propertiesNo data available
  • Oxidizing propertiesNo data available
  • Henry's Law Constant1.09 at 5 °C (average derived from six field experiments, Lüttke and Levsen, 1997)

Other safety information

Surface tension 38,2 mN/m at 50,0 °C

 

Relative vapor density

3,2 at 20 °C - (Air = 1.0)


SECTION 10: Stability and reactivity

Reactivity

Forms explosive mixtures with air on intense heating.

A range from approx. 15 Kelvin below the flash point is to be rated as critical.

The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.

Chemical stability

The product is chemically stable under standard ambient conditions (room temperature) .

Possibility of hazardous reactions

No data available

Conditions to avoid

Strong heating.

Incompatible materials

rubber, various plastics, various alloys, various metals, Strong oxidizing agents

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides Other decomposition products - No data available

In the event of fire: see section 5


SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity
No data available
LD50 Dermal - Rat - female - 660 mg/kg (OECD Test Guideline 402)
Skin corrosion/irritation
 
Serious eye damage/eye irritation
Eyes - Rabbit Result: Corrosive
(OECD Test Guideline 405)
Causes serious eye damage. Risk of blindness!
Respiratory or skin sensitization
Remarks: (IUCLID)
Germ cell mutagenicity
Suspected of causing genetic defects.
Mutagenicity (mammal cell test): chromosome aberration. Chinese hamster ovary cells
Result: positive
Mutagenicity (mammal cell test): micronucleus. Chinese hamster ovary cells
Result: positive
Carcinogenicity
This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification.
IARC: No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
May cause damage to organs through prolonged or repeated exposure. - Nervous system, Kidney, Liver, Skin
Aspiration hazard
No data available
Additional Information
RTECS: SJ3325000
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting, Circulatory collapse, tachypnea, paralysis, Convulsions, Coma., necrosis of mouth and G.I. Tract, Jaundice, respiratory failure, cardiac arrest
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Toxicity
LD50 orally in rats: 530 mg/kg (Deichmann, Witherup)

SECTION 12: Ecological information

Toxicity

 

Toxicity to fish
flow-through test LC50 - Onchorhynchus clarki - 8,9 mg/l - 96 h (US-EPA)

 

 

Toxicity to daphnia and other aquatic invertebrates

 

static test EC50 - Ceriodaphnia dubia (water flea) - 3,1 mg/l - 48 h (US-EPA)

 

Toxicity to algae
static test EC50 - Pseudokirchneriella subcapitata (algae) - 61,1 mg/l

 

- 96 h (US-EPA)

 

Toxicity to bacteria
static test IC50 - microorganisms - 21 mg/l - 24 h

 

Remarks: (ECHA)

Persistence and degradability

Biodegradability aerobic - Exposure time 100 h

Result: 62 % - Readily biodegradable. (OECD Test Guideline 301C)

Bioaccumulative potential

Bioaccumulation Danio rerio (zebra fish) - 5 h

at 25 °C - 2 mg/l(Phenol)

 

Bioconcentration factor (BCF): 17,5 (OECD Test Guideline 305)

Remarks: Does not bioaccumulate.

Mobility in soil

No data available

Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Other adverse effects

No data available


SECTION 13: Disposal considerations

Waste treatment methods

Incompatibilities

Phenol is incompatible with strong oxidizing agents, calcium hypochlorite, halogens, halogenated compounds, aluminum chloride, and nitrobenzene. Hot phenol can attack aluminum, lead, magnesium and zinc.

Product

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

 

Waste Disposal

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Incineration.


SECTION 14: Transport information

UN number

ADR/RID: 1671 IMDG: 1671

UN proper shipping name

ADR/RID: PHENOL, SOLID IMDG: PHENOL, SOLID IATA: Phenol, solid

Transport hazard class(es)

ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1

Packaging group

ADR/RID: II IMDG: II IATA: II

Environmental hazards

ADR/RID: yes IMDG Marine pollutant: yes IATA: no

Special precautions for user

No data available


SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals
China Catalog of Hazardous chemicals 2015:Listed. website: https://www.mem.gov.cn/
Measures for Environmental Management of New Chemical Substances
Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/
United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/
European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/
New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/
Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/
Korea Existing Chemicals List (KECL):Listed. website: http://ncis.nier.go.kr
EC Inventory:Listed.

SECTION 16: Other information

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Other Information

Other UN numbers: 2312 (molten); 2821 (solution).Depending on the degree of exposure, periodic medical examination is suggested.The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.

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