DEG (diethylene glycol)

CAS

Purity

CHARACTER

diethylene glycol, also known as diethylene glycol, chemical formula for C4H10O3, is a colorless or light yellow transparent oily liquid, molecular weight 106.12. It has good solubility and hygroscopicity, and can be miscible with water, ethanol and other solvents. As an important organic chemical raw material, diethylene glycol is widely used in the manufacture of polyester resins, polyurethane foams, brake fluids, plasticizers and dyes. At the same time, it is also an important component in industries such as medicine, cosmetics, printing and dyeing and biofuels. The versatility of diethylene glycol allows it to play an important role in different fields, facilitating industrial production.

APPLICATIONS

(1) As an important raw material in polyurethane synthesis, diethylene glycol can improve the flexibility of the material and play the role of crosslinking agent. It is widely used in furniture, automobiles, construction, textiles, waterproof coatings, adhesives and other fields.

(2) diethylene glycol is an important component of a variety of solvents, which can be used to dissolve dyes, paints, inks and resins, and is an important raw material for printing, dyes and coatings industries. At the same time, it can also be used as natural gas dehydration desiccant, aromatic hydrocarbon separation extractant, textile lubricant, softener, finishing agent, and nitrocellulose, grease and other solvents.

(3) In cosmetics and skin care products, diethylene glycol is often used as a moisturizer and softener, which can penetrate into the surface of the skin, maintain the humidity of the skin, and improve the moisturization and use of the product.

(4) As an intermediate, diethylene glycol can be used to synthesize other organic compounds, such as surfactants, plasticizers, lubricants, etc., and can also be used to synthesize fragrances and drugs, such as antibiotics, anti-tumor drugs, etc.

(5) In the field of pesticides, diethylene glycol can be used to prepare herbicides, such as glyphosate.

(6) diethylene glycol can also be used as brake fluid, capacitor fluid and other electrical fluids, as well as antifreeze components in compressor lubricating oil.

(7) In the food industry, diethylene glycol is used as a stabilizer and moisturizer, which can help maintain the freshness and taste of food, and can also be used as a disinfectant for food packaging materials.

(8) Diethylene glycol can also be used as a biofuel to replace petroleum, and mixed with other compounds to prepare renewable energy such as biodiesel, which helps to reduce environmental pollution.

INDICATORS

ABILITIES

1. Packing: barreled, scattered water
2. Logistics: car transportation, shipping
3. Payment request: EXW/FOB/FCA/CFR only accepted

HONORARY

Chinese name	diethylene glycol
English Name	DIETHYLENE GLYCOL
Alias	2-propanol diethylene glycol diethylene glycol diethylene glycol diethylene glycol ether diethylene Glycol Liquid dihydroxydiethyl ether diethylene glycol antifreeze DEG diethylene glycol bis (hydroxyethyl) ether 1-diethylene glycol bis (hydroxyethyl) ether diethylene Glycol-GCS (diethylene glycol) Diethylene Glycol (Diethylene Glycol) one shrink two (two) ethylene glycol diethylene Glycol (Diethylene Glycol) 2,2 '-dihydroxyethyl ether 2,2 '-Oxodiethanol 2,2 '-Oxydiethanol 2,2 '-Dihydroxydiethyl ether diethylene glycol bis (hydroxyethyl) ether 2,2 '-Oxodiethanol diethylene glycol (diethylene glycol) diethylene Glycol Monoethylene Glycol (Diethylene Glycol) 2-hydroxyethyl ether (or diethylene glycol, or diethylene glycol)
English alias	DEG NSC 36391 Brecolane NDG Diethyleneglyc 2,2'-oxyethanol 2,2'-Oxyethanol Diethylene glyco 2,2'-oxydiethanol 2,2'-oxydi-ethano DIETHYLENE GLYCOL Diethylene glycol 2,2'-oxybis-ethano 3-Oxa-1,5-pentanediol 3-Oxapentane-1,5-diol 2,2'-dihydroxyethylether 2,2'-Dihydroxyethyl ether 2-(2-Hydroxyethoxy)ethanol 2,2-Di(hydroxyethyl) ether 2-(2-hydroxyethoxy)-ethanol bis(beta-hydroxyethyl)ether 2-(2-hydroxy-ethoxy)-ethanol Bis(beta-hydroxyethyl) ether 3-OxapentaMethylene-1,5-diol Di-ethylene glycol,Ethylene diglycol 2,2'-Oxydiethanol Bis(2-hydroxyethyl) Ether Diethylene glycol, Bis(2-hydroxyethyl) ether
CAS	111-46-6
EINECS	203-872-2
Chemical formula	C4H10O3
molecular weight	106.12
InChI	InChI:1S/C4H10O3/c5-1-3-7-4-2-6/h5-6H,1-4H2
InChIKey	MTHSVFCYNBDYFN-UHFFFAOYSA-N
Density	1.118g/mLat 25°C(lit.)
melting point	−10°C(lit.)
boiling point	245°C(lit.)
Flash Point	143°C
water solubility	SOLUBLE
Vapor pressure	0.01mm Hg ( 20 °C)
steam density	2.14 (vs air)
solubility	H2O: 50 mg/mL at 20°C, clear, colorless
refractive index	n20/D 1.447(lit.)
acidity coefficient	14.03±0.10(Predicted)
PH value	5.5-7.0 (25℃, 50mg/mL in H2O)
Storage conditions	Keep in dark place,Sealed in dry,Room Temperature
Stability	hygroscopicity
Sensitivity	Hygroscopic
Appearance	Oily liquid
Color	colorless
Smell	Practically odorless.
Maximum wavelength (λmax)	λ: 260 nm Amax: ≤0.02λ: 280 nm Amax: ≤0.01
Merck	14,3119
BRN	969209
explosion limit value	2-12.3 percent
physicochemical properties	colorless, odorless, transparent, hygroscopic viscous liquid. There is a spicy sweetness. It is miscible with water, ethanol, acetone, ethyl ether and ethylene glycol, but not with benzene, toluene and carbon tetrachloride.
MDL No.	MFCD00002882
Dangerous Goods Signs	Xn-Hazardous Substances T-Toxic Substances Xi-Irritant Substances
Risk Terms	22-Harmful if swallowed.
Security terminology	46-If swallowed, seek medical advice immediately and show the container or label.
WGK Germany	1
RTECS	ID5950000
FLUKA BRAND F CODES	10
TSCA	Yes
Customs Number	29094100
Hazard Note	Toxic/Irritant
Upstream raw materials	ethylene oxide
Downstream Products	Toluene casein 4-benzylpiperidine 4-(4-methoxyphenyl) butyric acid 2,6-dichloroindophenol sodium 4-(2-thianyl) butyric acid diethylene glycol ether ursodeoxycholic acid 2,6-dichloro-4-aminophenol CSF series modified acrylic resin emulsion AC anti-mold coating agent diethylene glycol diethyl ether all-weather series resin 21-iodo -16 B- methyl pregnane -1,4,9(11) Triene-17A-ol-3, 20-dione N-ethylmorpholine 1,3-difluoro-2-propanol Thickener HD-70 diethylene glycol dibutyl ether diethylene glycol dibenzoate

Diethylene Glycol -Introduction

is hygroscopic, odorless, has a spicy sweet taste, soluble in water can be with most organic solvents, insoluble in benzene and carbon tetrachloride. Easy esterification, etherification.

Diethylene Glycol -Introduction

diethylene glycol is also called dihydrogen isopropanol. It is a colorless liquid, soluble in most organic solvents, and has a weak sweet taste. the following is on the nature of diethylene glycol, use, preparation and safety information presentation:

properties: 2

chemical properties: diethylene glycol is a kind of stable compounds, for air and water stability. It can react with many organic compounds, such as acid anhydrides, aldehydes, ketones, etc.

Uses: 1. Industrial Uses:
is widely used in pharmaceuticals, coatings, plastics, resins, rubber, solvents, dyes and inks and other industries, used as plasticizers, antifreeze, solvents, wetting agents, Adhesives, etc.

preparation method:
of diethylene glycol preparation method mainly has two kinds:
of 1. isopropanol oxidation method: through the isopropanol and catalyst a cesium oxide reaction, and then by oxidation reaction of diethylene glycol. 2.
propylene oxide hydrolysis method: propylene oxide and water reaction to generate diethylene glycol.

safety information: 1. diethylene glycol on the human body has certain
, long-term exposure may lead to poisoning, should avoid inhalation or skin contact. 2 in the use of the process should follow the safety procedures, such as wearing protective gloves, glasses and protective clothing.
3. Storage should be tightly sealed, away from fire and oxidant.
4. In the event of an accident or leak,
immediately take appropriate emergency measures, such as ventilation, isolation of leaks, etc., to avoid diffusion and reduce hazards.

Chemical Safety Data Sheet MSDS / SDS

Diethylene glycol

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

Product name: Diethylene glycol
CBnumber: CB0409579
CAS: 111-46-6
EINECS Number: 203-872-2
Synonyms: Diethylene glycol,deg

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
Uses advised against: none

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

Symbol(GHS)

Signal wordWarning

Precautionary statements

P330 Rinse mouth.

P501 Dispose of contents/container to..…

P270 Do not eat, drink or smoke when using this product.

P264 Wash skin thouroughly after handling.

P264 Wash hands thoroughly after handling.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

Hazard statements

H302 Harmful if swallowed

H320 Causes eye irritation

H373 May cause damage to organs through prolonged or repeated exposure

SECTION 3: Composition/information on ingredients

Substance

Product name: Diethylene glycol
Synonyms: Diethylene glycol,deg
CAS: 111-46-6
EC number: 203-872-2
MF: C4H10O3
MW: 106.12

SECTION 4: First aid measures

Description of first aid measures

General advice

Show this material safety data sheet to the doctor in attendance.

If inhaled

After inhalation: fresh air.

In case of skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.

In case of eye contact

After eye contact: rinse out with plenty of water. Remove contact lenses.

If swallowed

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media

Water Foam Carbon dioxide (CO2) Dry powder

Unsuitable extinguishing media

For this substance/mixture no limitations of extinguishing agents are given.

Special hazards arising from the substance or mixture

Carbon oxides Combustible.

Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating.

Development of hazardous combustion gases or vapours possible in the event of fire.

Advice for firefighters

In the event of fire, wear self-contained breathing apparatus.

Further information

Cool containers/tanks with water spray.Prevent fire extinguishing water from contaminating surface water or the ground water system.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

For personal protection see section 8.

Environmental precautions

Do not let product enter drains.

Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb? ). Dispose of properly. Clean up affected area.

Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

Precautions for safe handling

For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Storage conditions

Tightly closed.

hygroscopic Heat sensitive. Store under inert gas.

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits

Does not contain substances with occupational exposure limits.

Exposure controls

Personal protective equipment

Eye/face protection

Use equipment for eye protection tested and approved under appropriate

government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0,11 mm Break through time: 480 min

Material tested:Dermatril? (KCL 740 / Aldrich Z677272, Size M)

Splash contact Material: Nitrile rubber

Minimum layer thickness: 0,11 mm Break through time: 480 min

Material tested:Dermatril? (KCL 740 / Aldrich Z677272, Size M)

data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374

If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Body Protection

protective clothing

Respiratory protection

Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

These measures have to be properly documented.

Control of environmental exposure

Do not let product enter drains.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

Appearancecolorless viscous liquid
Odourodorless
Odour ThresholdNot applicable
pH6 - 8 at 200 g/l at 20 °C
Melting point/freezing pointMelting point/range: -10 °C - lit.
Initial boiling point and boiling range245 °C - lit.
Flash point138 °C - closed cup
Evaporation rateNo data available
Flammability (solid, gas)No data available
Upper/lower flammability or explosive limitsUpper explosion limit: 37 %(V) Lower explosion limit: 1,7 %(V)
Vapour pressure< 0,1 hPa at 25 °C
Vapour density3,66
Relative density1,118 at 20 °C
Water solubility1.000 g/l at 20 °C - miscible
Partition coefficient: n-octanol/waterlog Pow: -1,98 at 25 °C - Bioaccumulation is not expected., (IUCLID)
Autoignition temperature372 °C at 1.013,25 hPa
Decomposition temperatureDistillable in an undecomposed state at normal pressure.
ViscosityViscosity, kinematic: No data available Viscosity, dynamic: 30 mPa.s at 25 °C
Explosive propertiesNo data available
Oxidizing propertiesNo data available
λmaxλ: 260 nm Amax: ≤0.02
λ: 280 nm Amax: ≤0.01

Other safety information

Relative vapor density

3,66

SECTION 10: Stability and reactivity

Reactivity

Forms explosive mixtures with air on intense heating.

A range from approx. 15 Kelvin below the flash point is to be rated as critical.

Chemical stability

The product is chemically stable under standard ambient conditions (room temperature) .

Possibility of hazardous reactions

Violent reactions possible with: Strong oxidizing agents

Exothermic reaction with:

Strong acids

Conditions to avoid

Heating in air. Exposure to moisture. Strong heating.

Incompatible materials

Zinc

Hazardous decomposition products

In the event of fire: see section 5

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity

No data available
LD50 Dermal - Rabbit - 11.890 mg/kg Remarks:
(RTECS)

Skin corrosion/irritation

Skin - Rabbit
Result: No skin irritation Remarks:
(IUCLID)

Serious eye damage/eye irritation

Eyes - Rabbit
Result: No eye irritation Remarks:
(IUCLID)

Respiratory or skin sensitization

(Regulation (EC) No. 440/2008, Annex, B.6) Remarks:
(ECHA)

Germ cell mutagenicity

Ames test
Escherichia coli/Salmonella typhimurium Result: negative
OECD Test Guideline 474 Mouse - male - Bone marrow Result: negative

Carcinogenicity

IARC: No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

No data available

Specific target organ toxicity - single exposure

No data available

Specific target organ toxicity - repeated exposure

No data available

Aspiration hazard

No data available

Toxicity

LD50 in rats, guinea pigs (g/kg): 20.76, 13.21 orally (Smyth)

SECTION 12: Ecological information

Toxicity

Toxicity to fish

flow-through test LC50 - Pimephales promelas (fathead minnow) -

75.200 mg/l - 96 h Remarks: (ECHA)

Toxicity to bacteria

Persistence and degradability

No data available

Theoretical oxygen demand

1.510 mg/g Remarks: (Lit.)

Ratio BOD/ThBOD 1,3 - 10 %

Remarks: (Lit.)

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Other adverse effects

No data available

SECTION 13: Disposal considerations

Waste treatment methods

Product

See www.retrologistik.com for processes regarding the return of chemicals and

containers, or contact us there if you have further questions.

SECTION 14: Transport information

UN number

ADR/RID: - IMDG: - IATA: -

UN proper shipping name

ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods

Transport hazard class(es)

ADR/RID: - IMDG: - IATA: -

Packaging group

ADR/RID: - IMDG: - IATA: -

Environmental hazards

ADR/RID: no IMDG Marine pollutant: no IATA: no

Special precautions for user

Further information

Not classified as dangerous in the meaning of transport regulations.

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals

China Catalog of Hazardous chemicals 2015:Not Listed. website: https://www.mem.gov.cn/

Measures for Environmental Management of New Chemical Substances

European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/

United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/

Korea Existing Chemicals List (KECL):Listed. website: http://ncis.nier.go.kr

EC Inventory:Listed.

Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/

Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/

Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/

New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/

SECTION 16: Other information

Abbreviations and acronyms

CAS: Chemical Abstracts Service
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
IMDG: International Maritime Dangerous Goods
IATA: International Air Transportation Association
TWA: Time Weighted Average
STEL: Short term exposure limit
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
EC50: Effective Concentration 50%

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Other Information

Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.

Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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