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IPA (Isopropyl alcohol)

CAS

Purity

Category

Nickname

: 67-63-0

: 99.80%

: Alcohol Ether 

:iso-Propyl alcohol; iso-propanol; 2-propanol; isopropyl alcohol; PriOH; 2-Propanol; i-propyl alcohol; Isopropanol;
:iso-Propyl alcohol; iso-propanol; 2-propanol; isopropyl alcohol; PriOH; 2-Propanol; i-propyl alcohol; Isopropanol;
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size/weight : Bulk drum IOS Tank

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CHARACTER

isopropyl alcohol, chemical name 2-propanol, referred to as IPA, is a colorless and transparent liquid with a special smell, chemical formula C3H8O, molecular weight 60.10. It has good solubility and volatility, and can be miscible with water, alcohol, ether and other solvents. It is an important raw material in the fields of chemical industry, pharmacy, cosmetics and electronic industry. Isopropyl alcohol is used in the pharmaceutical industry to produce disinfectants, solvents and pharmaceutical intermediates; in the chemical industry, it is a key raw material for the production of chemicals such as acetone and hydrogen peroxide; at the same time, isopropyl alcohol is also widely used in the manufacture of coatings, printing inks and detergents. Its versatility and wide range of applications make isopropanol an indispensable raw material in industrial production.

APPLICATIONS

(1) isopropanol in the chemical industry as an important raw material, can produce acetone, hydrogen peroxide, methyl isobutyl ketone, diisobutyl ketone, isopropyl amine, isopropyl ether, isopropyl chloride and fatty acid isopropyl ester and chlorinated fatty acid isopropyl ester and other chemical products.

(2) isopropyl alcohol as a solvent, because it can be freely mixed with water and the dissolution of lipophilic substances than ethanol, is widely used in the dissolution of nitrocellulose, rubber, paint, shellac, alkaloids, etc., but also can be used in the production of coatings, inks, extractants, aerosol agents.

(3) Isopropyl alcohol also has important applications in the pharmaceutical and cosmetic industries. It is an intermediate or solvent for many drugs and cosmetics.

(4) Isopropyl alcohol can also be used as a chromatographic standard for the determination of barium, calcium, copper, magnesium, nickel, potassium, sodium, strontium, nitrous acid, cobalt and other metal ions.

(5) In the electronics industry, isopropyl alcohol is often used as a cleaning degretizer for cleaning electronic components and circuit boards.

(6) isopropyl alcohol can also be used as antifreeze, cleaning agent, blending gasoline additives, pigment production dispersant, printing and dyeing industry fixative, glass and transparent plastic antifogging agent.

(7) In the oil industry, isopropanol can be used as an extractant for cottonseed oil, and can also be used for degreasing of animal-derived tissue membranes.


INDICATORS

ABILITIES

1. Packing: barreled, scattered water
2. Logistics: car transportation, shipping
3. Payment request: EXW/FOB/FCA/CFR only accepted

HONORARY

Chinese name Isopropyl alcohol
English Name Isopropanol
Alias Isopropyl alcohol
2-Propanol
dimethyl methanol
medicinal isopropyl alcohol
high purity isopropyl alcohol
isopropyl alcohol standard solution
isopropyl alcohol (anhydrous)
2-Propanol (Isopropyl Alcohol)
2-propanol, dimethyl methanol
2-Propanol (anhydrous isopropanol)
isopropyl alcohol [for spectrophotometric determination]
isopropyl alcohol, 67-63-0, Aladdin reagent
English alias IPA
2-Propanol
Isopropanol
propan-1-ol
Isopropylalcohol
2-PROPANOL (IPA)
Isopropyl Alcohol
iso propyl alcohol
isopropanol anhydrous
Propan-2-ol-SPECIFIED
isopropanol molecular biology
2-PROPANOL ULTRA RESI-ANALYZED
CAS 67-63-0
EINECS 200-661-7
Chemical formula C3H8O
molecular weight 60.1
InChI InChI=1/C3H8O/c1-2-3-4/h4H,2-3H2,1H3
Density 0.785g/mLat 25°C(lit.)
melting point -89.5°C
boiling point 82°C(lit.)
Flash Point 53°F
water solubility miscible
Vapor pressure 33mm Hg ( 20 °C)
steam density 2.1 (vs air)
JECFA Number 277
solubility Water: Soluble (complete)
refractive index n20/D 1.377(lit.)
acidity coefficient 17.1(at 25℃)
Storage conditions Store at +5°C to +30°C.
Appearance low melting point solid
Specific Gravity approximate 0.785(20/20℃)(Ph.Eur.)
Color colorless
Smell Like ethyl alcohol; sharp, somewhat unpleasant; characteristic mild alcoholic; nonresidual.
Maximum wavelength (λmax) ['λ: 260 nm Amax: 0.02',
, 'λ: 280 nm Amax: 0.01']
Merck 14,5208
BRN 635639
explosion limit value 2-13.4%(V)
Exposure Limits TLV-TWA 980 mg/m3 (400 ppm); STEL 1225 mg/m3 (500 ppm) (ACGIH); IDLH 12,000 ppm (NIOSH).
physicochemical properties colorless transparent flammable liquid, like the smell of ethanol. With water, ethanol, ether, chloroform miscible.
Dangerous Goods Signs Xi-Irritant

F-Flammable Xn-Hazardous
Risk Terms R11-Highly flammable.
, R36-Irritating to eyes.
-R67-Vapor may cause drowsiness and dizziness.
-R40-Few reported carcinogenic consequences.
, R10-Flammable.
, R36/38-Irritating to eyes and skin.
Security terminology S7-Keep container sealed.
, S16-Keep away from ignition sources.
, S24/25-Avoid skin and eye contact. S26-
After contact with eyes, rinse immediately with plenty of water and seek medical advice.

, S36/37-Wear appropriate protective clothing and gloves.
Dangerous Goods Transport Number UN 1219 3/PG 2
WGK Germany 1
RTECS NT8050000
FLUKA BRAND F CODES 3-10
TSCA Yes
Customs number 2905 12 00
Hazard Class 3
Packing Group II
Upstream raw materials propylene phosphoric acid
Downstream Products isopropyl acetate isopropyl palmitate
 

Isopropyl Alcohol -Properties

Colorless transparent liquid. Slight smell of ethanol. It can be miscible with water, ethanol, ether and chloroform. Its vapor and air form an explosive mixture, which can cause combustion and explosion when exposed to open flame and high heat. Can react strongly with oxidants. In case of high heat, the internal pressure of the container increases, and there is a risk of cracking and explosion.

Isopropyl alcohol -preparation

, the raw material gas containing more than 50% propylene is absorbed by 75~6 ~ 85% concentrated sulfuric acid at 50 ℃ and low pressure to produce isopropyl hydrogen sulfate. Isopropyl hydrogen sulfate is then hydrolyzed to isopropanol. After crude distillation, the distillation tower is used to concentrate to 95%, then benzene is used to extract, water is separated and then distilled, and a finished product containing more than 99% isopropanol can be obtained. Alternatively, propylene and water were pressurized to 1.96 MPa respectively. And preheated to 200 degrees C, mixed and added to the reactor, hydration reaction. After neutralization and heat exchange, the reaction gas is sent to a high-pressure cooler and a high-pressure separator. Isopropanol in the gas phase is recovered by spraying with deionized water in a recovery tower. 85% ~ 87% isopropanol aqueous solution is distilled by a crude distillation tower, concentrated to 95% by a distillation tower, and then extracted with benzene to obtain more than 99% isopropanol.

Isopropyl alcohol -standard

This product is 2-propanol.

Isopropyl alcohol -Properties

  • This product is colorless clear liquid.
  • This product and water, methanol, ethanol or ether can be arbitrarily miscible.

relative density

The relative density (general 0601 Wechsler gravity scale method) is 0. 785~0.788.

Refractive rate

The refractive index (general 0622) is 1. 376~1. 379.

Last update: 2022-01-01 11:22:18

Isopropyl alcohol -use

determination of barium, calcium, copper, magnesium, nickel, potassium, sodium, strontium, nitrite, cobalt and other reagents. Chromatographic analysis standards. As chemical raw materials, it can produce acetone, hydrogen peroxide, methyl isobutyl ketone, diisobutyl ketone, isopropyl amine, isopropyl ether, isopropyl ether, isopropyl chloride, and fatty acid isopropyl ester and chlorinated fatty acid isopropyl ester. In fine chemicals, it can be used to produce isopropyl nitrate, isopropyl xanthate, triisopropyl phosphite, aluminum triisopropoxide, pharmaceuticals and pesticides. As a solvent, it can be used in the production of paints, inks, extractants, aerosol agents, etc. It can also be used as an antifreeze, detergent, additive for blending gasoline, dispersant for pigment production, fixing agent for printing and dyeing industry, antifogging agent for glass and transparent plastic, etc.

Isopropyl Alcohol -Identification

  1. Take lm l of this product, add iodine test solution 2m l and sodium hydroxide test solution 2ml, shake, produce yellow precipitate, and produce iodoform special odor.
  2. Take this product 5ml, add potassium dichromate test solution 20ml, and then carefully add sulfuric acid 5ml, in the water bath slowly heating, the gas can make immersed in salicylaldehyde-ethanol solution (1:10) and 30% sodium hydroxide solution filter paper reddish brown.
  3. The infrared absorption spectrum of this product should be consistent with that of the control (general 0402).

Isopropyl alcohol -safety

Rats oral LD50:5.8 g/kg. Headache, drowsiness and eye, nose and throat irritation may occur when exposed to high concentrations of steam. The staff shall be well protected and the workplace shall be well ventilated. Store in a cool, ventilated warehouse. Keep away from fire and heat source. Prevent direct sunlight. Keep container sealed. Should be stored separately from the oxidizer.

Isopropyl Alcohol -Check

Acidity

Take 50.0ml of this product, add 100ml of water, add 2 drops of phenolphthalein indicator liquid, drop sodium hydroxide titrant (O .lm o l/L) until the pink is 30 seconds without fading, and consume sodium hydroxide titrant (0. lm o l/L) shall not exceed 1. 4ml.

Solution Clarity and Color

Take this product 1.0ml, add water 20ml, mix well, let stand for 5 minutes, according to law inspection (general rule 0901 and general rule 0902) , the solution should be clear and colorless.

Absorbance

Take this product, according to ultraviolet-visible spectrophotometry (general 0401) determination, in 230nm, 250nm, 270nm, 290nm and 3l0nm wavelength absorbance shall not be greater than 0.30, 0.10, 0.03, 0.0 2 and 0.01.

water insoluble matter

Take this product 2 .0 m l, add water 8 m l, shake, place 5 minutes, the solution should be clear.

non-volatile matter

Take 50.0ml of this product, place it in a 105°C constant weight evaporating dish, evaporate it on a water bath, and then dry it at 105°C for 1 hour. The remaining residue shall not exceed 1. 0mg [0.002% (g /m l) ].

easy oxide

Take 10.0ml of this product, place it in a colorimetric tube, adjust the temperature to 15°C, add potassium permanganate titration solution (0.02mQl/L)0.50ml, plug tightly, shake well, and stand at 156C for 15 minutes. The pink of the solution shall not completely disappear.

easy carbonization

Take sulfuric acid 5ml, placed in dry colorimetric Zan, cooled to 1 0V, shake while dropping 5. 0ml of this product (keep the solution temperature not higher than 20°C ) , the color of the solution and yellow No. 1 standard colorimetric solution (general rules 0901) comparison, shall not be deeper.

carbonyl compound

Take 0.50ml of this product, place it in a plug colorimetric tube, add 2,4-dinitrophenylhydrazine solution (take 2,'dinitrophenylhydrazine 50mg, add 2ml of hydrochloric acid, dilute to 50ml with carbonyl-free methanol *, shake well) lm l, plug tightly, shake well, let stand for 30 minutes, add 8ml of pyridine, 2m l of water and potassium hydroxide-methanol solution (take 15ml of 33% potassium hydroxide solution, add 50ml)2ml of carbonyl-free methanol, shake well, stand for 30 minutes, dilute to 25ml with carbonyl-free methanol, shake well, and the resulting dark red and carbonyl compound (CO) impurity standard solution®0. 50ml shall not be deeper after treatment according to the same method.

Moisture

Take this product, according to the moisture determination method (general 0832 the first method 1) determination, moisture content shall not exceed 0 .2%.

Benzene and related substances

According to gas chromatography (general 0521).

  • Chromatographic Conditions and System Suitability Test A capillary column with 6% cyanopropylphenyl-94% dimethylsiloxane as stationary liquid (or similar polarity) is programmed to increase the temperature at an initial temperature of 4 0 1, maintained for minutes, and increased to 240°C at a rate of 10T per minute for 10 minutes. The inlet temperature is 280°C and the detector temperature is 28CTC. The resolution of the n-propanol peak from the 2-butanol peak in the control solution (a) should be not less than 10.
  • Determination Method Take this product as the test solution U ) ; Accurately measure 2-butanol lm l, place in a 50ml volumetric flask, dilute to scale with this product, shake well, accurately measure 5ml, place in a 100ml volumetric flask, dilute to scale with this product, shake well, and use it as the test solution (B); Accurately measure 0.5ml of 2-butanol and ml of n-propanol each in a 50ml volumetric flask, dilute to scale with this product, shake well, accurately measure 5ml, place in a 50ml volumetric flask, dilute to scale with this product, shake well, as control solution u); Precision measure benzene 100 1, place in a 100ml volumetric flask, dilute to scale with this product, shake well, precision measure 0.2ml, place in a 100ml volumetric flask, dilute to scale with this product, shake well, as control solution (B). Precisely measure the control solutions (a) and (B) and the test solutions (a) and (B), respectively, inject them into the gas chromatograph, and record the chromatogram. If benzene is contained in the test solution (a), its peak area shall not be greater than 0.5 times (0.0 0 2%) of the peak area of benzene in the control solution (B); The sum of the peak areas of other impurities in the test solution (B) shall not be greater than 3 times (0.3%) of the peak area of 2-butanol in the control solution (a).

Isopropyl alcohol -categories

Pharmaceutical excipients, solvents.

Isopropyl Alcohol -Storage

Shading, airtight preservation.

Isopropyl Alcohol -Introduction

Isopropyl alcohol is a colorless and transparent liquid with a pungent odor at room temperature. It has a low boiling point and density, soluble in water, alcohols and ether solvents. Isopropanol is a polar solvent that can be used to dissolve many organics.

isopropyl alcohol has a variety of applications. It is an important intermediate in the synthesis of chemicals and can be used to synthesize esters, ethers and alcohols. Isopropanol is also a common choice for industrial use as a solvent and cleaning agent.

Isopropanol -Chemical Properties

Colorless transparent liquid, similar to ethanol and acetone mixture
to the smell of the substance, can be miscible with alcohol, ether, chloroform and water, can dissolve alkaloids, rubber, shellac, rosin, synthetic resin and other organic and some inorganic substances, and water to form an azeotrope, insoluble in salt solution. At room temperature, it can start to burn, and the mixture of steam and air can easily form an explosive mixture.
isopropanol is prone to peroxide production and sometimes requires identification prior to use. The method is: take 10% isopropanol, add 1ml of 0.5 potassium iodide solution, 1:5 dilute hydrochloric acid ML and several drops of starch solution, shake well for 1 minute, if blue or blue-black is peroxidation. It is similar to ethanol and propanol, but has the properties of a secondary alcohol.

Isopropanol -Preparation

Isopropyl alcohol is a colorless and transparent organic compound, its preparation method mainly has the following several kinds:
1. from isopropionaldehyde
reduction: isopropionaldehyde and reducing agent (such as hydrogen, metal sodium, etc.) reaction, at the appropriate temperature and pressure conditions, can be prepared by isopropanol.


2. from propylene preparation: propylene and water heating reaction, the hydrated propionaldehyde, and then through the dehydration reaction, can be prepared isopropanol.

3. from propyne gas preparation: propyne gas is subjected to catalytic hydrogenation reaction to obtain propylene, and then according to the above method to prepare isopropanol.

Isopropyl alcohol -Basic data

molecular structure data
molar refractive index: 17.44
molar volume (m3/mol):75.9
isotonic capacity (90.2K):165.6
surface tension (dynes/cm):22.6
polarizability (10-24cm3):6.91
calculated Chemical Data
hydrophobic parameter calculation reference value (XlogP):0.3
number of hydrogen bond donors: 1
number of hydrogen bond acceptors: 1
number of rotatable chemical bonds: 0
topological Molecular Polar Surface Area (TPSA):20.2
number of heavy atoms: 4
surface charge: 0
Complexity: 10.8
Isotope Atomic Number: 0
to Determine Atomic Stereo Center Number: 0 Uncertain Atomic Stereo Center Number: 0
to Determine Chemical Bond Stereo Generation Center Number: 0 Uncertain Chemical Bond Stereo Generation Center Number: 0
to
Covalent Bond Unit Number: 1

Isopropyl Alcohol -Hazards and Protection

isopropyl alcohol is an organic solvent, which has certain toxicity and harmfulness. The following are about the hazards of isopropyl alcohol and protective measures:

hazards:
1. Irritating effect on skin and eyes, may cause redness, burning pain and inflammation;
2. Excessive inhalation of isopropyl alcohol vapor may cause dizziness, nausea, vomiting, difficulty breathing, and nervous system damage;
3. Long-term exposure or high intake of isopropyl alcohol may cause damage to the liver, kidneys and central nervous system.

Protective measures:
1. When using isopropyl alcohol, wear protective gloves, safety goggles, protective clothing and other protective equipment to avoid contact with skin and eyes;
2. When using isopropyl alcohol in a closed environment, ensure good ventilation to avoid inhaling excessive vapor;
3. Avoid contact with fire sources, high temperature substances or oxidants, isopropyl alcohol is flammable;
4. When a leak occurs, the source of the leak should be stopped immediately, and the appropriate adsorbent should be used for adsorption and cleaning;
5. Properly store isopropyl alcohol and avoid mixing with other chemicals.

Isopropyl Alcohol-Supply and Demand

Isopropanol is an organic solvent, which is also widely used in chemical reactions and industrial production. According to market demand, the supply and demand of isopropanol has been in balance.

demand, isopropyl alcohol is mainly used in coatings, cleaning agents, glue and other industries. With the development of the global economy and the increase of industrial manufacturing, the demand for isopropyl alcohol in these fields is also increasing. Especially in the automotive industry, building materials and art protection, the demand for isopropyl alcohol has increased.
the
supply side, the production of isopropanol is mainly carried out by synthesis. At this stage, many countries and regions in the world have isopropanol production capacity, such as the United States, China, Germany and so on. Among them, China is one of the largest producers of isopropanol.

Isopropyl Alcohol -Introduction

1. nature:
isopropyl alcohol is colorless transparent liquid, with special alcohol smell.
It is soluble in water and a variety of organic solvents, such as
ether, methanol and alcohols.
3. Isopropyl alcohol is flammable and can form an explosive mixture with oxygen.

Uses:
Isopropanol is widely used in industrial fields, especially as a solvent for coatings, inks, resins and dyes. 2. Isopropanol in the preparation of certain chemicals
act as a reducing agent or catalyst.
3. In the laboratory, isopropyl alcohol is also commonly used as a general organic solvent.


preparation method:
of isopropyl alcohol can be prepared by the following two methods:
of 1. from propylene deoxygenation preparation: propylene at high temperature catalytic hydrogenation, generate isopropyl alcohol.
, 2. from acetone reduction preparation: acetone and hydrogen in the presence of catalyst reaction, the formation of isopropanol.

Safety Information: 1. Isopropyl alcohol is irritating and should avoid direct contact with skin and eyes.

2. in the operation of isopropyl alcohol, should pay attention to avoid inhalation of its vapor, so as not to cause poisoning. 3. with flammability, should be away from open flame and high temperature area, storage should be sealed preservation.
4 in the treatment of isopropyl alcohol waste liquid, need to take appropriate protective measures to prevent environmental pollution.

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Chemical Safety Data Sheet MSDS / SDS

Isopropyl alcohol

 

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: Isopropyl alcohol
  • CBnumber: CB8854102
  • CAS: 67-63-0
  • EINECS Number: 200-661-7
  • Synonyms: IPA,Isopropyl Alcohol

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

  • Symbol(GHS)
  • Signal wordDanger
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P337+P313 IF eye irritation persists: Get medical advice/attention.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Hazard statements
H225 Highly Flammable liquid and vapour
H319 Causes serious eye irritation
H336 May cause drowsiness or dizziness

SECTION 3: Composition/information on ingredients

Substance

  • Product name: Isopropyl alcohol
  • Synonyms: IPA,Isopropyl Alcohol
  • CAS: 67-63-0
  • EC number: 200-661-7
  • MF: C3H8O
  • MW: 60.1

SECTION 4: First aid measures

Description of first aid measures

General advice
Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air. Call in physician.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.
In case of eye contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
If swallowed
After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media
Carbon dioxide (CO2) Foam Dry powder
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.

Special hazards arising from the substance or mixture

Carbon oxides Combustible.

Pay attention to flashback.

Vapors are heavier than air and may spread along floors.

Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures.

Advice for firefighters

In the event of fire, wear self-contained breathing apparatus.

Further information

Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system.

 


SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.

Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.

Environmental precautions

Do not let product enter drains. Risk of explosion.

Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb? ). Dispose of properly. Clean up affected area.

Reference to other sections

For disposal see section 13.


SECTION 7: Handling and storage

Precautions for safe handling

Advice on safe handling

Avoid generation of vapours/aerosols.

Advice on protection against fire and explosion

Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.

Hygiene measures

Change contaminated clothing. Wash hands after working with substance. For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Storage conditions

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition.

Handle and store under inert gas. Hygroscopic.

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated


SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits
Does not contain substances with occupational exposure limits.

Exposure controls

Personal protective equipment
Eye/face protection

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Skin protection

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0,4 mm Break through time: 480 min

Material tested:Camatril? (KCL 730 / Aldrich Z677442, Size M)

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Splash contact Material: Chloroprene

Minimum layer thickness: 0,65 mm Break through time: 120 min Material tested:KCL 720 Camapren?

Body Protection

Flame retardant antistatic protective clothing.

Respiratory protection

Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

These measures have to be properly documented.

Control of environmental exposure

Do not let product enter drains. Risk of explosion.

Exposure limits
TLV-TWA 980 mg/m3 (400 ppm); STEL 1225 mg/m3 (500 ppm) (ACGIH); IDLH 12,000 ppm (NIOSH).

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

  • Appearancecolorless liquid
  • Odouralcohol-like
  • Odour Threshold1 ppm
  • pHat 20 °C neutral
  • Melting point/freezing pointMelting point/range: -89,5 °C
  • Initial boiling point and boiling range82 °C
  • Flash point12,0 °C - closed cup
  • Evaporation rate3,0
  • Flammability (solid, gas)No data available
  • Upper/lower flammability or explosive limitsUpper explosion limit: 13,4 %(V) Lower explosion limit: 2 %(V)
  • Vapour pressure43 hPa at 20 °C
  • Vapour density2,07
  • Relative density0,785 g/mL at 25 °C
  • Water solubilityat 20 °C soluble
  • Partition coefficient: n-octanol/waterlog Pow: 0,05 - Bioaccumulation is not expected.
  • Autoignition temperature425,0 °C
  • Decomposition temperatureDistillable in an undecomposed state at normal pressure.
  • ViscosityViscosity, kinematic: No data available Viscosity, dynamic: 2,2 mPa.s at 20 °C
  • Explosive propertiesNo data available
  • Oxidizing propertiesNo data available
  • λmaxλ: 260 nm Amax: 0.02
    λ: 280 nm Amax: 0.01

Other safety information

Minimum ignition energy

0,65 mJ

Conductivity < 0,1 μS/cm

Surface tension 20,8 mN/m at 25,0 °C

 

Relative vapor density

2,07

 

 


SECTION 10: Stability and reactivity

Reactivity

Vapors may form explosive mixture with air.

Chemical stability

Reacts with air to form peroxides.

The product is chemically stable under standard ambient conditions (room temperature) .

Possibility of hazardous reactions

No data available

Conditions to avoid

Warming.

Incompatible materials

Acid anhydrides, Aluminum, Halogenated compounds, Acids, Strong oxidizing agents

Hazardous decomposition products

In the event of fire: see section 5


SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity
LD50 Oral - Rat - 5.840 mg/kg
(OECD Test Guideline 401)
LC50 Inhalation - Rat - male and female - 4 h - 37,5 mg/l (OECD Test Guideline 403)
LD50 Dermal - Rabbit - 12.800 mg/kg Remarks:
(RTECS)
Skin corrosion/irritation
Skin - Rabbit
Result: No skin irritation - 4 h (OECD Test Guideline 404)
Serious eye damage/eye irritation
Eyes - Rabbit Result: Eye irritation
(OECD Test Guideline 405)
(Regulation (EC) No 1272/2008, Annex VI)
Respiratory or skin sensitization
Buehler Test - Guinea pig Result: negative
(OECD Test Guideline 406)
Germ cell mutagenicity
Ames test
Salmonella typhimurium Result: negative
In vitro mammalian cell gene mutation test Chinese hamster ovary cells
Result: negative
OECD Test Guideline 474
Mouse - male and female - Bone marrow
Result: negative
Carcinogenicity
This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification.
IARC: No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
Inhalation, Oral - May cause drowsiness or dizziness. - Central nervous system Remarks:
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Acute inhalation toxicity - Central nervous system
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Toxicity
LD50 orally in rats: 5.8 g/kg (Smyth, Carpenter)

SECTION 12: Ecological information

Toxicity

 

Toxicity to fish
flow-through test LC50 - Pimephales promelas (fathead minnow) - 9.640 mg/l - 96 h

 

 

 

Toxicity to daphnia and other aquatic invertebrates

 

(OECD Test Guideline 203)

EC50 - Daphnia magna (Water flea) - 13.299 mg/l - 48 h Remarks: (IUCLID)

 

Toxicity to algae
IC50 - Desmodesmus subspicatus (green algae) - > 1.000 mg/l - 72 h

 

Remarks: (IUCLID)

 

 

Toxicity to bacteria
EC5 - Pseudomonas putida - 1.050 mg/l - 16 h

 

Remarks: (Lit.)

 

Persistence and degradability

Biodegradability aerobic - Exposure time 5 d

Result: 53 % - Readily biodegradable. (Directive 67/548/EEC, Annex V, C.6)

Theoretical oxygen demand

2.400 mg/g Remarks: (Lit.)

Ratio BOD/ThBOD 49 %

Remarks: (IUCLID)

Bioaccumulative potential

No bioaccumulation is to be expected (log Pow <= 4).

Mobility in soil

No data available

Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Other adverse effects

No data available


SECTION 13: Disposal considerations

Waste treatment methods

Product

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

 

Incompatibilities

Incompatible with oxidizing agents such as hydrogen peroxide and nitric acid, which cause decomposition. Isopropyl alcohol may be salted out from aqueous mixtures by the addition of sodium chloride, sodium sulfate, and other salts, or by the addition of sodium hydroxide.


SECTION 14: Transport information

UN number

ADR/RID: 1219 IMDG: 1219

UN proper shipping name

ADR/RID: ISOPROPANOL IMDG: ISOPROPANOL IATA: Isopropanol

Transport hazard class(es)

ADR/RID: 3 IMDG: 3 IATA: 3

Packaging group

ADR/RID: II IMDG: II IATA: II

Environmental hazards

ADR/RID: no IMDG Marine pollutant: no IATA: no

Special precautions for user

No data available


SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals
China Catalog of Hazardous chemicals 2015:Listed. website: https://www.mem.gov.cn/
Measures for Environmental Management of New Chemical Substances
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/
EC Inventory:Listed.
European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/
Korea Existing Chemicals List (KECL):Listed. website: http://ncis.nier.go.kr
New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/
Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/
United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/
Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/

SECTION 16: Other information

Abbreviations and acronyms

  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • CAS: Chemical Abstracts Service
  • EC50: Effective Concentration 50%
  • IATA: International Air Transportation Association
  • IMDG: International Maritime Dangerous Goods
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • STEL: Short term exposure limit
  • TWA: Time Weighted Average

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Other Information

Use of alcoholic beverages enhances the harmful effect.
Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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